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Q:
What is the pH of a 0. 40 M H2Se solution that has the stepwise dissociation constants
Ka1= 1.3 10-4andKa2= 1.0 10-11?
A) 2. 14
B) 3.89
C) 4. 28
D) 5. 57
Q:
Calculate the pH of a 0. 60 M H2SO3, solution that has the stepwise dissociation constants
Ka1= 1.5 10-2and Ka2= 6.3 10-8.
A) 1.02
B) 1.06
C) 1.82
D) 2.04
Q:
Calculate the pH of a 0. 080 M carbonic acid solution, H2CO3(aq), that has the stepwise dissociation constants Ka1= 4.3 10-7and Ka2= 5.6 10-11.
A) 1.10
B) 3.73
C) 6.37
D) 10.25
Q:
Potassium hydrogen phthalate (molar mass = 204.2 g/mol)is one of the most commonly used acids for standardizing solutions containing bases. KHP is a monoprotic weak acid with Ka= 3.91 10-6. Calculate the pH of the solution that results when 0. 50 g of KHP is dissolved in enough water to produce 25.0 mL of solution.
A) 2.05
B) 3. 21
C) 4. 40
D) 5.41
Q:
What is the hydronium ion concentration of a 0. 150 M hypochlorous acid solution withKa= 3.5 10-8? The equation for the dissociation of hypochlorous acid is:HOCl(aq) + H2O(l) H3O+(aq) + OCl-(aq).A) 1.9 10-4 MB) 7.2 10-4 MC) 2.8 10-5 MD) 7.2 10-5 M
Q:
What is the hydronium ion concentration of a 0. 500 M acetic acid solution with Ka= 1.8 10-5? The equation for the dissociation of acetic acid is:CH3CO2H(aq) + H2O(l) H3O+(aq) + CH3CO2-(aq).A) 3.0 10-2MB) 4.2 10-2MC) 3.0 10-3MD) 4.2 10-3M
Q:
What is the pH of a solution prepared by mixing 100.00 mL of 0.020 M Ca(OH)2with 50.00 mL of 0. 300 M NaOH? Assume that the volumes are additive.
A) 13.05
B) 13.10
C) 13.28
D) 13.58
Q:
What is the pH of a solution prepared by mixing 100.00 mL of 0.20 M HCl with 150.00 mL of 0. 10 M HCl? Assume that the volumes are additive.
A) 0. 17
B) 0. 52
C) 0. 85
D) 1.70
Q:
What is the pH of a solution prepared by diluting 100.00 mL of 0.020 M Ba(OH)2with enough water to produce a total volume of 250.00 mL?
A) 1.80
B) 2. 10
C) 11.90
D) 12.20
Q:
What is the pH of a solution prepared by diluting 20.00 mL of 0.10 M HCl with enough water to produce a total volume of 100.00 mL?
A) 1.00
B) 1. 70
C) 2.00
D) 3.40
Q:
What is the pH of a solution prepared by dissolving 0. 45 grams of solid CaO (lime) in enough water to make 2.00 L of aqueous Ca(OH)2(limewater)?CaO(s) + H2O(l) -> Ca2+(aq) + 2 OH-(aq)A) 2.10B) 2.40C) 11.60D) 11.90
Q:
What is the pH of a 0.0 40 M Ba(OH)2solution?
A) 1.10
B) 1.40
C) 12.60
D) 12.90
Q:
What is the hydroxide ion concentration of a lye solution that has a pH of 9.20?
A) 6.31 10- 10M
B) 1.58 10- 5M
C) 4.80 M
D) 9.20 M
Q:
What is the hydronium ion concentration of an acid rain sample that has a pH of 3. 45?
A) 2.82 10-11M
B) 3.55 10-4M
C) 3. 45 M
D) 10. 55 M
Q:
What is the hydronium ion concentration and the pH for an aqueous solution of NH3that has a hydroxide ion concentration of 2.25 10-2M?
A) 4.44 10- 12M and 2.65
B) 4.44 10- 12M and 11.35
C) 4.44 10- 13M and 1.65
D) 4.44 10- 13M and 12.35
Q:
What is the hydroxide ion concentration and the pH for a hydrochloric acid solution that has a hydronium ion concentration of 1.50 10-2M?
A) 6.67 10- 12M, 2.82
B) 6.67 10- 12M, 11.18
C) 6.67 10- 13M, 1.82
D) 6.67 10- 13M, 12.17
Q:
Calculate the pH for an aqueous solution of acetic acid that contains 2.15 10-3M hydronium ion.
A) 4.65 10-12 M
B) 2.15 10-3 M
C) 2. 67
D) 11. 33
Q:
A solution with a hydroxide ion concentration of 4.15 10- 6M is ________ and has a hydrogen ion concentration of ________.
A) acidic, 2.41 10- 8M
B) acidic, 2.41 10- 9M
C) basic, 2.41 10- 8M
D) basic, 2.41 10- 9M
Q:
A solution with a hydrogen ion concentration of 3.25 10- 6M is ________ and has a hydroxide ion concentration of ________.
A) acidic, 3.08 10- 8M
B) acidic, 3.08 10- 9M
C) basic, 3.08 10- 8M
D) basic, 3.08 10- 9M
Q:
Calculate the hydroxide ion concentration in an aqueous solution that contains 3.50 10- 4M in hydronium ion.
A) 2.86 10- 3M
B) 2.86 10- 10M
C) 2.86 10- 11M
D) 3.50 10- 11M
Q:
Calculate the hydronium ion concentration in an aqueous solution that contains 2.50 10- 6M in hydroxide ion.
A) 4.00 10- 7M
B) 4.00 10- 8M
C) 4.00 10- 9M
D) 5.00 10- 9M
Q:
Which Bronsted-Lowry acid is not considered to be a strong acid in water?A) H IB) H BrC) H2S O3D) HNO3
Q:
When dissolved in water, which compound is generally considered to be an Arrhenius acid?
A) HNO2
B) KOH
C) LiF
D) CH3OH
Q:
BF3and NH3undergo a Lewis acid-base reaction forming an adduct. Which picture below correctly represents the curved arrow notation for the initial Lewis acid-Lewis base interaction in this reaction; what is the Lewis acid and the Lewis base?A) Picture (1) is correct; NH3is the Lewis acid and BF3is the Lewis base.B) Picture (2) is correct; BF3is the Lewis acid and NH3is the Lewis base.C) Picture (3) is correct; NH3 is the Lewis acid and BF3is the Lewis base.D) Picture (4) is correct; BF3is the Lewis acid and NH3is the Lewis base.
Q:
CO2reacts with H2O to form HCO3-and H+. Which picture below correctly represents the curved arrow notation for the initial Lewis acid-Lewis base interaction in this reaction; what is the Lewis acid and the Lewis base? (1) (2)
A) Picture (1) is correct; H2O is the Lewis acid and CO2is the Lewis base.
B) Picture (1) is correct; CO2is the Lewis acid and H2O is the Lewis base.
C) Picture (2) is correct; H2O is the Lewis acid and CO2is the Lewis base.
D) Picture (2) is correct; CO2is the Lewis acid and H2O is the Lewis base.
Q:
SO3reacts with H2O to form H2SO4. Which picture below correctly represents the curved arrow notation for the initial Lewis acid-Lewis base interaction in this reaction; what is the Lewis acid and the Lewis base? A) Picture (1) is correct; H2O is the Lewis acid and SO3is the Lewis base.
B) Picture (1) is correct; SO3is the Lewis acid and H2O is the Lewis base.
C) Picture (2) is correct; H2O is the Lewis acid and SO3is the Lewis base.
D) Picture (2) is correct; SO3is the Lewis acid and H2O is the Lewis base.
Q:
Of the elements indicated on the periodic table shown above, which forms the weakest oxoacid acid with the formula H2XO3or HXO3, where X = A, B, C, or D?
A) A
B) B
C) C
D) D
Q:
Of the elements indicated on the periodic table shown above, which forms the strongest oxoacid acid with the formula H2XO3or HXO3, where X = A, B, C, or D?
A) A
B) B
C) C
D) D
Q:
Of the elements indicated on the periodic table shown above, which forms the weakest binary acid, H2X or HX, where X = A, B, C, or D?
A) A
B) B
C) C
D) D
Q:
Of the elements indicated on the periodic table shown above, which forms the strongest binary acid, H2X or HX, where X = A, B, C, or D?
A) A
B) B
C) C
D) D
Q:
Which picture represents a basic salt?
A) (1)
B) (2)
C) (3)
D) None of these
Q:
Which picture represents a neutral salt?
A) (1)
B) (2)
C) (3)
D) None of these
Q:
Which picture represents an acidic salt?
A) (1)
B) (2)
C) (3)
D) None of these
Q:
The following pictures represent solutions of three salts NaA (A-= X-, Y-, or Z-); water molecules and Na+ions have been omitted for clarity. Arrange the three A-ions in order of decreasing base strength. A) X-> Y-> Z-
B) X-> Z-> Y-
C) Y-> Z-> X-
D) Z-> Y-> XZ-
Q:
Arrange the conjugate bases (A-= X-, Y-, or Z-) in order of increasing value of Kb.
A) Kb(Z-) < Kb(Y-) < Kb(X-)
B) Kb(Y-) < Kb(Z-) < Kb(X-)
C) Kb(Z-) < Kb(X-) < Kb(Y-)
D) Kb(X-) < Kb(Z-) < Kb(Y-)
Q:
Arrange the conjugate bases (A-= X-, Y-, or Z-) in order of increasing base strength.
A) Z-< Y-< X-
B) Y-< Z-< X-
C) Z-< X-< Y-
D) X-< Z-< Y-
Q:
Arrange the acids in order of increasing pH.
A) HZ < HY < HX
B) HY < HZ < HX
C) HZ < HX < HY
D) HX < HZ < HY
Q:
Arrange the acids in order of increasing value of percent dissociation.
A) HZ < HY < HX
B) HY < HZ < HX
C) HZ < HX < HY
D) HX < HZ < HY
Q:
Arrange the acids in order of increasing value of Ka.
A) Ka(HZ) < Ka(HY) < Ka(HX)
B) Ka(HY) < Ka(HZ) < Ka(HX)
C) Ka(HZ) < Ka(HX) < Ka(HY)
D) Ka(HX) < Ka(HZ) < Ka(HY)
Q:
Arrange the acids in order of increasing acid strength.
A) HZ < HY < HX
B) HY < HZ < HX
C) HZ < HX < HY
D) HX < HZ < HY
Q:
Which of the above pictures represents a solution of a diprotic acid H2A for which Ka1= ï‚¥and Ka2is exceptionally small. (Water molecules have been omitted for clarity.)
A) picture (a)
B) picture (b)
C) picture (c)
D) picture (d)
Q:
Which of the above pictures represents a solution of a weak diprotic acid H2A for which
Ka1>> Ka2? (Water molecules have been omitted for clarity.)
A) picture (a)
B) picture (b)
C) picture (c)
D) picture (d)
Q:
Which acid solution has the lowestpH?
A) HX
B) HY
C) HZ
D) All have the same pH.
Q:
Which acid has the lowestpercent dissociation?
A) HX
B) HY
C) HZ
D) All have the same percent dissociation.
Q:
Which acid has the smallestvalue of Ka?
A) HX
B) HY
C) HZ
D) All have the same Kavalue.
Q:
Which acid, if any, is a strong acid?
A) All are strong acids.
B) HX and HZ
C) HY
D) None are strong acids.
Q:
Arrange the three acids in order of increasing acid strength.
A) HZ < HY < HX
B) HY < HZ < HX
C) HZ < HX < HY
D) HX < HZ < HY
Q:
Identify the Br∅nsted-Lowry acid/base conjugate pairs.
A) (1)/(2) and (3)/(4)
B) (1)/(3) and (2)/(4)
C) (1)/(4) and (2)/(3)
Q:
Identify the Bronsted-Lowry acid/base conjugate pairs.A) (1)/(2) and (3)/(4)B) (1)/(3) and (2)/(4)C) (1)/(4) and (2)/(3)
Q:
Identify the Bronsted-Lowry bases.A) (1) and (3)B) (1) and (4)C) (2) and (3)D) (2) and (4)
Q:
Identify the Br∅nsted-Lowry acids.
A) (1) and (3)
B) (1) and (4)
C) (2) and (3)
D) (2) and (4)
Q:
Identify the Bronsted-Lowry bases.A) (1) and (3)B) (1) and (4)C) (2) and (3)D) (2) and (4)
Q:
Identify the Bronsted-Lowry acids.A) (1) and (3)B) (1) and (4)C) (2) and (3)D) (2) and (4)
Q:
Which one of the following is expected to be the strongest Lewis acid?
A) Fe
B) Fe+
C) Fe2+
D) Fe3+
Q:
Identify the set of Lewis acids.
A) BH3, BF3, Cu2+, CO2
B) Cl-, OH-, NH3, H2O
C) H3PO4, H2PO4-, HPO42-, PO43-
D) CH3-, NH2-, OH-, F-
Q:
The compound BF3can be described as a(n) ________.A) Arrhenius acidB) Bronsted-Lowry acidC) Lewis acidD) Lewis base
Q:
Which one of the following is leastable to behave as a Lewis base?
A) CH3NH2
B) (CH3)2NH
C) (CH3)3N
D) (CH3)3NH+
Q:
Which one of the following is notconsidered to be a Lewis base?
A) H2O
B) NH3
C) NH4+
D) Cl-
Q:
For Cu2+and CO2, which will behave as a Lewis acid toward OH-in water?
A) only Cu2+
B) only CO2
C) Cu2+and CO2
D) neither Cu2+nor CO2
Q:
Identify the Lewis acid that acts as a reactant in the following reaction.Co(H2O)63+(aq) + 6 NH3(aq) -> Co(NH3)63+(aq) + 6 H2O(l)A) Co(H2O)63+B) Co3+C) NH3D) H2O
Q:
Identify the Lewis acid that acts as a reactant in the following reaction.Fe(H2O)63+(aq) + 6 CN-(aq) -> Fe(CN)63-(aq) + 6 H2O(l)A) Fe3+B) H2OC) CN-D) Fe(H2O)63+
Q:
What is the strongest acid among the following?
A) CH3CO2H
B) ClCH2CO2H
C) Cl2CHCO2H
D) Cl3CCO2H
Q:
What is the strongest acid among the following?
A) HIO
B) HIO2
C) HIO3
D) HIO4
Q:
What is the strongest acid of the following?
A) HOI
B) HOBr
C) HOCl
D) All are equivalent.
Q:
What is the strongest acid among the following?
A) H2SO3
B) H2SO4
C) H2SeO3
D) H2SeO4
Q:
What is the strongest base among the following?
A) ClO-
B) ClO2-
C) ClO3-
D) ClO4-
Q:
Which acid of the following set has the strongest conjugate base?
A) CH4
B) NH3
C) H2O
D) HF
Q:
What is the weakest acid among the following?
A) SiH4
B) PH3
C) H2S
D) HCl
Q:
What is the strongest acid among the following?
A) HF
B) HCl
C) H2O
D) H2S
Q:
What is the strongest acid among the following?
A) H2O
B) H2S
C) H2Se
D) H2Te
Q:
What is the strongest acid among the following?
A) HF
B) HCl
C) HBr
D) HI
Q:
What is the identity of M in the hydrate M(H2O)6n+that has the 0.10 M solution with the highest pH?
A) Li+
B) Na+
C) Mg2+
D) Al3+
Q:
What is the identity of M in the hydrate M(H2O)6n+that has the 0.10 M solution with the lowestpH?
A) Li+
B) Na+
C) Mg2+
D) Al3+
Q:
Which one of the following salts, when dissolved in water, produces the solution with the lowestpH?
A) NaCl
B) NH4Cl
C) MgCl2
D) AlCl3
Q:
Equal volumes of 0.10 M NH3(Kb= 1.8 10-5) and 0.10 M HCN (Ka= 4.9 10-10) are mixed together. Will the resulting solution be acidic, basic, or neutral?
A) acidic
B) basic
C) neutral
D) insufficient information to solve
Q:
Calculate the pH of a 0.100 M CH3NH3Cl solution. Kbfor methylamine, CH3NH2, is 3.7 10-4.
A) 2.22
B) 5.78
C) 8.22
D) 11.78
Q:
Calculate the pH of a of 0.100 M KBrO solution. Kafor hypobromous acid, HBrO, is 2.0 10-9.
A) 3.15
B) 4.85
C) 9.15
D) 10.85
Q:
Calculate the pH of a 0.100 M NaCH3CO2solution. Kafor acetic acid, CH3CO2H, is 1.8 10-5.
A) 2.87
B) 5.13
C) 8.87
D) 11.13
Q:
Which one of the following salts, when dissolved in water, produces the solution with a pH closestto 7.00?
A) NH4Cl
B) BaO
C) NaHSO4
D) RbI
Q:
Which one of the following salts, when dissolved in water, produces the solution with the highestpH?
A) KI
B) KBr
C) KCl
D) KF